Product ID:COMPOUND A-97P
MSDS Date:06/15/1992
FSC:6850
NIIN:00N042642
MSDS Number: BRNCS

MADISON CHEMICAL CO INC

3141 CLIFTY DR
MADISON, IN 47250-0599
US

Emergency Phone: 812-273-6000;800-424-9300(CHEMTREC)

Info Phone: 812-265-2703;812-273-6213

Preparer: STEVEN T. HALE

Cage: 60142

MADISON CHEMICAL CO INC

125 MADISON, IN 47250 US

Cage: 60142

STODDARD SOLVENT; (MINERAL SPIRITS)

CAS: 8052-41-3

RTECS: WJ8925000

Fraction By Weight: 85%

OSHA PEL 500 PPM

ACGIH TLV: 100 PPM; 9293

ETHANOL, 2-BUTOXY-; (2-BUTOXYETHANOL)

CAS: 111-76-2

RTECS: KJ8575000

Fraction By Weight: 3-5%

OSHA PEL S, 50 PPM

ACGIH TLV: S, 25 PPM; 9293

LD50 LC50 Mixture:NONE LISTED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CONTACTED AREAS MAY EXHIBIT IRRIT.
OVEREXP TO MISTS/VAPS MAY CAUSE DIZZ, DROW, HDCH, NAUS.MASS OVEREXP
MAY CAUSE UNCON, DEATH. INGEST MAY CAUSE IRRIT, NAUS, VOMIT, &
DIARR. ASPIR INTO LUNGS CAN CAUSE CHEM PNEUM WHICH CAN BE FATAL.
PRLNGD &RPTD INHAL EXPOS TO ELEV CONCS OF STODDARD SOLV HAS BEEN
ASSOC (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: W/KIDNEY DMG IN RATS. CHRONIC OVEREXP
TO 2-BUTOXYETHANOL HAS APPARENTLY BEEN FOUND TO CAUSE ANEMIA, LIVER
ABNORM, KIDNEY DMG, LUNG DMG, & BLOOD ABNORM. ANIMAL STUDIES
CLEARLY DEMONSTRATED DO SE-RELATED ADVERSE EFTS ON CNS,
HEMATOPOIETIC TISS, BLOOD, KIDNEYS & LIVER, ASSOC W/ADMIN OF
2-BUTOXYETHANOL. (SUPDAT)
Medical Cond Aggravated by Exposure:NONE LISTED BY MANUFACTURER.

First Aid:EYES & SKIN: IMMED FLUSH W/LRG QTYS OF COOL WATER
CONTINUOUSLY FOR AT LST 15 MINS. CALL PHYS. REMOVE CONTAMD CLTHG &
SHOES. DO NOT PUT CONTAM CLTHG & SHOES BACK ON. WASH CLTHG & SHOES
THORO IN SOAP & WATER; RINSE REPEATEDLY IN CLEAN WATER & DRY
BEFORE REUSE. INGEST: DO NOT INDUCE VOMIT. GIVE WATER. NEVER GIVE
ANYTHING BY MOUTH TO AN UNCON PERS. CALL PHYS. INHAL: MOVE SUBJECT
TO FRESH AIR. (SUPDAT)

Flash Point Method:CC
Flash Point:103F,39C
Lower Limits:1.1%
Upper Limits:6.1%
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. WATER SPRAY MAY BE INEFFECTIVE BUT MAY BE USED TO COOL CLOSED
CONTAINERS. IF WATER IS USED, USE FOG NOZZ.
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR AND MAY
TRAVEL ALONG GROUND AND BE IGNITED BY IGNITION SOURCES DISTANT FROM
MATERIAL HANDLING POINT.

Spill Release Procedures:CONTAIN LIQUID SPILLS WITH SAND AND ABSORB ON
SODA ASH. AVOID BREATHING VAPORS. REMOVE SOURCES OF IGNITION.
VENTILATE AREA. USE NON-SPARKING TOOLS. DISPOSE WITH SOLIDS WASTES.
SEE WASTE DISPOSAL METHO D. DO NOT DISCHARGE TO DRAIN.
Neutralizing Agent:NONE LISTED BY MANUFACTURER.

Handling and Storage Precautions:STORE AWAY FROM HEAT, OPEN FLAMES AND
OTHER IGNITION SOURCES, AND STRONG OXIDIZERS. CLEAN UP SPILLS
IMMEDIATELY. KEEP BUNG TIGHTLY CLOSED.
Other Precautions:DO NOT FLAME CUT, BRAZE, OR WELD IN VINCINITY. NORMAL
FOR COMBUST MATL. AVOID FREE FALL OF LIQ; GROUND CNTNRS WHEN
POURING. VAP HARMFUL! AVOID PRLNGD BRTHG OF VAP.AVOID PRLNGD/RPTD
CONT W/SKIN. HARMFU L/ FATAL IF SWALLOWED. CONTAINS (SUPDAT)

Respiratory Protection:USE NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR
WHERE AIRBORNE EXPOSURE IS EXCESSIVE.
Ventilation:USE GOOD VENTILATION. LOCAL EXHAUST IS RECOMMENDED IF TLV'S
ARE EXCEEDED.
Protective Gloves:RUBBER GLOVES.
Eye Protection:CHEMICAL SAFETY GOGGLES .
Other Protective Equipment:AS REQUIRED TO AVOID CONTACT. EYEWASH
FACILITY AND EMERGENCY SHOWER SHOULD BE IN CLOSE PROXIMITY.
Work Hygienic Practices:NONE LISTED BY MANUFACTURER.
Supplemental Safety and Health
EFFECTS OF OVEREXPOSURE: (EXTRACTED FROM DHHS (NIOSH) PUBLICATION NO.
90-118) . FIRST AID PROCEDURES: IF BREATHING IS DIFFICULT,
ADMINISTER OXYGEN. GET MEDICAL ATTENTION. OTHER PRECAUTIONS: STOD
DARD SOLVENT AND 2-BUTOXYETHANOL. FOR INDUSTRIAL USE ONLY. KEEP OUT
OF REACH OF CHILDREN.

HCC:F4
Boiling Pt:B.P. Text:>300F,>149C
Vapor Pres:2.7 @ 20C
Vapor Density:4.7
Spec Gravity:0.77 (H2O=1)
Evaporation Rate & Reference:0.03 (ETHER=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:TAN LIQUID WITH MILD SOLVENT ODOR.
Percent Volatiles by Volume:90

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:EXCESS HEAT, SPARKS, OPEN FLAMES.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
VARIOUS HYDROCARBONS, AND OXIDES OF SULFUR.

Waste Disposal Methods:NORMAL FOR ALIPHATIC HYDROCARBONS AND GLYCOL
ETHERS. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.